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Beilstein J. Org. Chem. 2014, 10, 2886–2891, doi:10.3762/bjoc.10.305
Graphical Abstract
Scheme 1: Synthetic approaches to benzo[b]furans from 2-alkynylphenols, ketones and 2-fluorophenylacetylene d...
Scheme 2: Copper-promoted reaction of 2-fluorophenylacetylene derivatives to yield benzo[b]furans. Reaction c...
Scheme 3: Copper-promoted synthesis of 2,2'-bisbenzofuran derivatives.
Scheme 4: Intramolecular competition experiments.
Scheme 5: Copper-promoted synthesis of benzo[b]thiophenes.
Scheme 6: Proposed mechanism for the annulation reaction.